CUTICLE DECEMENTATION AND BUCKLING 221 8b Figure 8. Surfaces of decemented cuticles treated with a 3% aqueous solution of polyethylenimide (PEI) after three cycles of wetting/blow drying. 8a x770 8b x2500. to cause severe cuticle shape distortion. In Figures 8a and 8b are shown decemented cuticles treated with PEI after three cycles of wetting/blow drying. In these figures it can be clearly seen that after blow/drying the decemented cuticles appear severely distorted. From these observations it can be inferred that decemented cuticles can be distorted or reglued depending on the mechanical properties of the dry polymer. CONCLUSIONS The experiments show that strain cycles at low extensions in dry hair fibers produce lifting and buckling at the cuticle edges. Strain-cycling experiments with swollen fibers indicate that decementation and buckling of the cuticles is caused by circular compres- sion stresses on the cuticular envelope. It is also shown that this type of damage can be prevented and repaired by using appropriate hair swelling actives or by pretreating the fibers with appropriate polymeric substances capable of recementing the cuticles. ACKNOWLEDGMENTS The author wishes to thank Ann Harder for her valuable technical assistance and Herb Eldestein for his helpful discussions. REFERENCES (1) J. A. Swift Fine details on the surface of human hair, Int. J. Cosmet. Sci., 13, 143-159 (1991). (2) J. A. Swift and A. C. Brown, The critical determination of fine changes in the surface architecture of human hair due to cosmetic treatment, J. Soc. Cosmet. Chem., 23, 695-702 (1972).
222 JOURNAL OF COSMETIC SCIENCE (3) J. A. Swift, "The Hair Surface," in Hair Research, Orfanos, Montagna, Stuttgen, Eds. (Springer-Verlag, Berlin, Heidelberg, 1981). (4) C. R. Robbins, Chemical and Physical Behavior of Human Hair, 3rd ed. (Springer-Verlag, New York, 1994), pp. 211-226. (5) V. N. E. Robinson, A study of damaged hair, J. Soc. Cosmet. Chem., 27, 155-161 (1976). (6) M. L. Garcia, J. A. Epps., R. S. Yane, and L. D. Hunter, Normal cuticle wear patterns in human hair, J. Soc. Cosmet. Chem., 29, 155-178 (1978). (7) E. Hoting, M. Simmermann, and S. Hilterhaus-Bong, Photochemical alterations in human hair. I. Artificial irradiation and investigations of hair proteins, J. Soc. Cosmet. Chem., 46, 85-99 (1995). (8) M. L. Tate, Y. K. Kamath, S. B. Reutsch, and H. D. Weigmann, Quantification and prevention of hair damage, J. Sot'. Cosmet. Chem., 44, 347-371 (1993). (9) C. R. Robbins and C. H. Kelly, Weathering of human hair, Text. Res. J., 37, 337 (1967). (10) S. B. Reutsch and H. D. Weigmann, Mechanism of tensile stress release in the keratin fiber cuticle. I. J. Soc. Cosmet. Chem., 47, 13-26 (1996). (11) An experimental product of Croda. (12) A commercial Croda product with the name of Crodasone W. (13) A commercial Croda product with the name of Crodasone Cystine. (14) M. Gamez-Garcia, Morphological Changes in Human Hair Cuticles Upon the Simultaneous Action of Cyclical Mechanical and Thermal Stresses: Their Relevance to Grooming Practices, presented at the Annual Conference of the Society of Cosmetic Chemists, December 1997 M. Gamez-Garcia, The cracking of human hair cuticles by cyclical thermal stresses, J. Cosmet. Sci., 49, 141-153 (1998). (15) W. A. Nash, Strength of Materials, Schaum's Outline Series (McGraw-Hill, Inc., New York, 1972), pp. 7, 16, 17. (16) F. Ziegler, Ed., Mechanics of Solids and Fluids (Springer-Verlag, New York, 1981). (17) H. Baumann, in Fibrous Proteins: Scientifi6 Industrial, and Medical Aspects, D. A.D. Parry and L. K. Creamer, Eds. (Academic Press, London, 1979), pp. 1,299.
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