136 JOURNAL OF COSMETIC SCIENCE Henderson, I. Hinberg, and R. Little, NTP Center for the Evaluation of Risks to Human Reproduc- tion: Phthalates expert panel report on the reproductive and developmental toxicity of butyl benzyl phthalate, Reprod. Toxicol., 16, 45 3-487 (2002). (35) K.-Y. Lee, M. Shibutani, H. Takagi, N. Kato, S. Takigami, C. Uneyama, and M. Hirose, Diverse developmental toxicity of di-n-butyl phthalate in both sexes of rat offspring after maternal exposure during the period from late gestation through lactation, Toxicology, 203, 221-238 (2004). (36) R. N. Wine, L.-H. Li, L. H. Barnes, D. K. Gulati, and R. E. Chapin, Reproductive toxicity of di-n- butylphthalate in a continuous breeding protocol in Sprague-Dawley rats, Environ. Health Perspect., 105, 102-107 (1997). (37) J. Doull, R. Cauley, C. Elcombe, B. G. Lake, J. Swenberg, C. Wilkenson, G. Williams, and M. A. van Gernert, A cancer risk assessment of di(2-ethylhexyl)phthalate: Application of the new U.S. EPA risk assessment guidelines, Regttl. Toxicol. Pharrnacol., 29, 327-357 (1999). (38) R. L. Melnick, Is peroxisome proliferation an obligatory precursor step in the carcinogenicity of di(2-ethylhexyl)phthalate (DEHP)?, Environ. Health Perspect., 109, 437-442 (2001). (39) S. M. Duty, N. P. Singh, M. J. Silva, D. B. Barr, J. W. Brock, L. Ryan, R. F. Herrick, D. C. Christiani, and R. Hauser, The relationship between environmental exposures to phthalates and DNA damage in human sperm using the neutral comet assay, Environ. Health Perspect., 111, 1164-1169 (2003). (40) Y. Tomonari, Y. Kurata, T. Kawasuso, R. David, G. Gans, M. Tsuchitani, and M. Katoh, Testicular toxicity study of di(2-ethylhexyl) phthalate (DEHP) in juvenile common marmoset, Toxicologist, 72, 385 (2003). (41) FDA, 2004 priorities (http:l/www.cfsan.fda.gov/-dms!cfsan404.html). (42) R. Battle and C. Nerin, Application of single-drop microextraction to the determination of dialkyl phthalate esters in food simulants,J. Chromatogr. A, 1045, 29-35 (2004). (43) G. Prokupkova, K. Holadova, J. Poustka, and J. Hajslova, Development of a solid-phase microexcrac- tion method for the determination of phthalic acid esters in water, Anal. Chim. Acta, 457, 211-233 (2002). (44) 0. A. Teirlynck and M. T. Rosseel, Determination of di- and mono (2-ethylhexyl) phthalate in plasma by gas chromatography,]. Chromatogr., 342, 399-405 (1985). (45) K. S. Andersen and J. Lam, Simple and direct method for quantitative gas chromatographic determi- nation of di(2-ethylhexyl) phthalate in edible oils,]. Chromatogr., 169, 101-106 (1979). (46) Y.-Q. Cai, G.-B. Jiang, J.-F. Liu, and Q.-X. Zhou, Multi-walled carbon nanotubes packed cartridge for the solid-phase extraction of several phthalate esters from water samples and their determination by high performance liquid chromatography, Anal. Chim. Acta, 494, 149-156 (2003). (47) K. Mitani, S. Narimatsu, F. Izushi, and H. Kataoka, Simple and rapid analysis of endocrine disruptors in liquid medicines and intravenous injection solutions by automated in-tube solid-phase microex- traction/high performance liquid chromatography,]. Pharrn. Biomed. Anal., 32, 469-478 (2003). (48) K. Kambia, T. Dine, B. Gressier, A.-F. Germe, M. Luyckx, C. Brunet, L. Michaud, and F. Gottrand, High-performance liquid chromatographic method for the determination of di(2-ethylhexyl) phthalate in total parenteral nutrition and in plasma,]. Chrornatogr. B, 755, 297-303 (2001). (49) S. Jara, C. Lysebo, T. Greibrokk, and E. Lundanes, Determination of phthalates in water samples using polystyrene solid-phase extraction and liquid chromatography quantification, Anal. Chim. Acta, 407, 165-171 (2000). (50) L. Brossa, R. M. Maree, F. Borrull, and E. Pocurull, Application of on-line solid-phase extraction-gas chromatography-mass spectrometry to the determination of endocrine disruptors in water samples,]. Chrornatogr. A, 963, 287-294 (2002). (51) R. Chaler, L. Canton, M. Vaquero, and]. 0. Grimalt, Identification and quantification of n-octyl esters of alkanoic and hexanedioic acids and phthalates as urban wastewater markers in biota and sediments from estuarine areas, J. Chrornatogr. A, 1046, 203-210 (2004). (52) E. Cortazar, 0. Zuloaga, J. Sanz, J. C. Raposo, N. Etxebarria, and L. A. Fernandez, MultiSimplex optimisation of the solid-phase microextraction-gas chromatographic-mass spectrometric determina- tion of polycyclic aromatic hydrocarbons, polychlorinated biphenyls and phthalates from water samples,]. Chrornatogr. A, 978, 165-175 (2002). (53) K. Luks-Betlej, P. Popp, B. Janoszka, and H. Paschke, Solid-phase microextraction of phthalates from water,]. Chrornatogr. A, 938, 93-101 (2001). (54) T. Niino, T. Ishibashi, T. Itho, S. Sakai, H. Ishiwata, T. Yamada, and S. Onodera, Simultaneous determination of phthalate di- and monoesters in poly(vinylchloride) products and human saliva by gas chromatography-mass spectrometry, J. Chrornatogr. B, 780, 35-44 (2002).
PHTHALATE ESTERS IN COSMETIC PRODUCTS 137 (55) C. Y. Chen, A. V. Ghule, W. Y. Chen, C. C. Wang, Y. S. Chiang, and Y. C. Ling, Rapid identification of phthalates in blood bags and food packaging using ToF-SIMS, Appl. Surface Sci., 231-232, 447-451 (2004). (56) A. 0. Earls, I. P. Axford, and J. H. Braybrook, Gas chromatography-mass spectrometry determination of the migration of phthalate plasticisers from polyvinyl chloride toys and childcare articles, ]. Chromatogr. A, 983, 237-246 (2003). (57) B. C. Blount, K. E. Milgram, M. J. Silva, N. A. Malek, J. A. Reidy, L. L. Needham, and J. W. Brock, Quantitative detection of eight phthalate metabolites in human urine using HPLC-APCI-MS/MS, Anal. Chem., 72, 4127-4134 (2000). (58) H. M. Koch, L. M. Gonzalez-Reche, and J. Angerer, On-line clean-up by multidimensional liquid chromatography-electrospray ionization tandem mass spectrometry for high throughput quantifica- tion of primary and secondary phthalate metabolites in human urine,]. Chromatogr. B, 784, 169-182 (2003). (59) M. J. Silva, A. R. Slakman, J. A. Reidy, J. L. Preau, Jr., A. R. Herbert, E. Samandar, L. L. Needham, and A. M. Calafat, Analysis of human urine for fifteen phthalate metabolites using automated solid- phase extraction,]. Chromatogr. B, 805, 161-167 (2004). (60) K. Inoue, T. Higuchi, F. Okada, H. Iguchi, Y. Yoshimura, A. Sato, and H. Nakazawa, The validation of column-switching LC/MS as a high-throughput approach for direct analysis of di(2-ethylhexyl) phthalate released from PVC medical devices in intravenous solution,]. Pharm. Biomed. Anal., 31, 1145-1152 (2003). (61) W. Hancock, B. A. Rose, and D. D. Singer, The determination of diethyl phthalate in cosmetic preparations, Analyst, 91, 449-454 (1966). (62) E.W. Godly and A. E. Mortlock, The determination of di-n-alkyl phthalates in cosmetic preparations by gas-liquid chromatography, Analyst, 98, 493-501 (1973). (63) R. L. Yates and D. C. Havery, Determination of phenol, resorcinol, salicylic acid, and a-hydroxy acids in cosmetic products and salon preparations,]. Cosmet. Sci., 50, 315-325 (1999). (64) Code of Federal Regulations, 21, 701.3(a). (65) Cosmetic Ingredient Review: Final report on the safety assessment of dibutyl phthalate, dimethyl phthalate, and diethyl phthalate,J. Am. Coll. Toxicol., 4, 267-303 (1985). (66) Cosmetic Ingredient Review: Final report on the safety assessment of butyl benzyl phthalate,]. Am. Coll. Toxicol., 11, 1-23 (1992). (67) R.H. McKee, J. H. Butala, R. M. David, and G. Gans, NTP center for the evaluation of risks to human reproduction reports on phthalates: Addressing the data gaps, Reprod. Toxicol., 18, 1-22 (2004). (68) Scientific Committee on Cosmetics and Non-food Products (http:!leuropa.eu.intlcomm!health!ph_risk/ committees/sccpldocumentslout246_en.pd/). (69) Scientific Committee on Cosmetics and Non-food Products (http:!!europa.eu.intlcomm!health/jJh_risk! committees/sccp!documentslout287_en.pd/). (70) R. Hauser, S. Duty, L. Godfrey-Bailey, and A. M. Calafat, Medications as a source of human exposure to phthalates, Environ. Health Perspect., 112, 751-753 (2004). (71) R. C. Scott, P.H. Dugard, J. D. Ramsay, and C. Rhodes, In vitro absorption of some o-phthalate diesters through human and rat skin, Environ. Health Perspect., 74, 223-227 (1987).
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