ANALYSIS OF SHAMPOOS 897 SUMMARY A comprehensive literature survey of methods for the analysis of sham- poos has been presented. A proposed scheme of analysis for complex modern shampoos using a combination of solvent extraction, ion exchange separation, and infrared spectroscopy is presented. (Received February 2, 1972) REFERENCES (1) Schwartz, A.M., and Perry, J. W., Surface Active Agents: Their Chemistry and Technology, Vol. I, Interscience Publishers, Inc., New York, 1949, p. 444. (2) Schwartz, A.M., Perry, J. W., and Berch, Julian, Surface Active Agents and Detergents, Vol. II, Interscience Publishers, Inc., New York, 1958, p. 621. (3) Behrman, H. T., The Scalp in Health and Disease, The C. V. Mosby Co., St. Louis, Mo., 1952, pp. 125-9. (4) Schwartz, A.M., Perry, J. W., and Berch, Julian, Ibid., pp. 323, 334 if. (5) Rosen, M. J., and Goldsmith, H. A., Systematic Analysis of Surface Active Agents, Interscience Publishers, Inc., New York, 1960, p. 238 if. (6) Smith, W. B., The analysis of synthetic detergents, d. Soc. Cosmet. Chem., 14• 513-27 (1963). (7) van der Hoeve, J. A., Analysis of textile auxiliary products, J. Soc. Dyers Colour., 70• 145- 54 (1954). (8) Drewry, J., Quantitative examination of detergents by paper chromatography, Analyst, 88, 225-31 (1963). (9) Rosenberger, G. A., The rapid analysis of shampoo powders containing soap, Seifensieder- Ztg., 65, 118-20 (1938) Chem. Abstr., 32, 3649 (3), (1938). (10) Ram, S., Analysis of washing powders containing sulfates and sulfonates, Analyst, 67• 162 (1942) Chem. Abstr., 36, 5581 (2), (1942). (11) Parisot, Andre, Rapid industrial analysis of soap and soap-like products, Olearia, 3• 13-20 (1949) Chem. Abstr., 44, 2263 (c) (1949). (12) Newburger, S. H., The analysis of shampoos, J. Ass. Oj•Sc. Agr. Chem., 41,664-8 (1958). (13) Bush, S. J., Chemical analysis in the cosmetic industry, J. Soc. Cosmet. Chem., 10• 258-71 (1959). (14) Neu, G. E., Techniques of foam measurement, Ibid., 11,390-414 (1960). (15) Mapstone, G. E., The determination of water in shampoos by distillation, Ibid., 12• 397- 400 (1961). (16) Sallee, E. M., Ed., Oj•Scial and Tentative Methods of the American Oil Chemists' Society, AOCS, Chicago, Ill., 1970, Method Fla-44. (17) Oriol Pascual, D. J., Problems encountered in determining the viscosity of shampoos• Parrum. Cosmet. Sayohs, 9, 171-8 (1966) Chem. Abstr., 65, 8662 (h), (1966). (18) Benk, E., and Treiber, H., Identifying phosphoric acid emulsifiers in shampoos containing egg products, Riechst., Aromen, Koerperpflegem., 16• 306-8, 310 (1966) Chem. Abstr., 66• 13997 (t), (1967). (19) Newburger, S. H., A Manual of Cosmetic Analysis, Association of Official Agricultural Chemists, Washington, D.C., 1962, pp. 36-43 (20) Puttnam, N. A., Lee, S., and Baxter, B. H., Application of attenuated total reflectance infrared spectroscopy to toilet articles and household products. I. Qualitative analysis, J. Soc. Cosmet. Chem., 16, 607-15 (1965).
898 JOURNAL OF THE SOCIETY OF COSMETIC CHEMISTS (21) (22) (23) (24) (25) (26) Puttnam, N. A., Baxter, B. H., Lee, S., and Stott, P. L., Application of attenuated total reflectance infrared spectroscopy to toilet articles and household products. II. Quan- titative analysis, Ibid., 177 9-16 (1966 ). Schwarz, G. W. G., Possibilities and limitations of shampoo analysis, Ibid., 17, 737-44 (1966). Epton, S. R., New methods for the rapid titrimetric analysis of sodium alkyl sulfates and related compounds, Trans. Faraday Soc., 44, 226 (1948). Barr, T., Oliver, J., and Stubbings, W. V., The determination of surface active agents in solution, J. Soc. Chem. Ind., 67, 45-8 (1948). Yoshikawa, K., Nishina, T., and Takehana, K., Thin-layer chromatography of deter- gents. I. Simultaneous analysis of commercial liquid shampoos and liquid dishwashing detergents by TLC, Yukagaku, 15, 65-72 (1966) Chem. Abstr., 64, 11445 (h), (1966). Fairchild, (2. M., and Kabacoff, B. L., Analytical chemistry of zinc pyrithione, VI, pre- sented at semi-annual meeting of the Society of Cosmetic Chemists, New York, May 8, 1969. (27) Graber, M. B., Domsky, I. I., and Ginn, M. E., Thin-layer chromatographic method for identification of germicides in personal care products, J. Amer. Oil Chem. Soc., 46, 529-31 (1969). (28) Jones, J. H., Newburger, S. H., Champion, M. H., Kottemann, C. M., and Gross, F. C., Gas chromatography in cosmetic analysis, Proc. Joint Conf. Cosmet. $ci., 75-89 (1968), Toilet Goods Assoc., Washington, D.C. Chem. Abstr., 70, 109096 (g), (1969). (29) Gross, F. C., and Jones, J. H., Determination of propylene glycol in cosmetics by gas chromatography, J. Ass. Offc. Anal. Chem., 50, 1284-6 (1967). (30) Fairchild, C. M., Analytical chemistry in the cosmetics industry, Anal. Chem., $9 (10), 22A-24A, 26A, 28A, 30A, 32A, and 34A (1967). (31) Jones, J. H., General colorimetric method for determination of small quantities of sul- fonated or sulfated surface-active compounds, •/. Ass. Offc. Agr. Chem., 28• 398-409 (1945 ) Chern. Abstr., $9, 3951 (q), (1945). (32) Kecskemethy, L., Szamoskozi, Z., Weber, C., and Bozoki, G., Qualitative and quan- titative analysis of perfumes by uv spectrophotometry, Olaj, Szappan, Kozmet, 17, 23-6 (1968). (33) Ginn, M. E., and Church, C. L., New columnar and mixed-bed ion exchange methods for surfactant analysis and purification, Anal. Chem. $1,551-5 (1959). (34) Ross, L. U., and Blank, E. W., Error in the determination of the active ingredient in de- tergent products, J. Amer. Oil Chern. Soc., $,}, 70 (1957).
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