76 JOURNAL OF THE SOCIETY OF COSMETIC CHEMISTS (6) (7) (8) (9) (lo) (11) (12) (13) (14) (15) (16) (17) (18) (19) (20) (21) (22) (23) (24) (25) (26) (27) N. N. Bezinger, G. D. Galpern, N. G. Ivanova, and G. A. Sameshkina, Use of differentiating nonaqueous solvents for the determination of amine N-oxides, Zh. Anal. Khim., 23, 1538-1545 (1968). C. N. Wang and L. D. Metcalfe, The determination of unreacted amines in long chain amine oxides by potentiometric titration, J. Am. Oil Chem. Soc., 62, 558-560 (1985). L. D. Metcalf, Potentiometric titration of long chain amine oxides using alkyl halide to remove tertiary amine interference, Anal. them., 34, 1849 (1962). L. D. Metcalfe, The analysis of cationic surfactants, J. Am. Oil Chem. Sot., 61, 363-366 (1984). R. T. Brooks and P. D. Sternglanz, Titanometric determination of the N-oxide group in pyridine- N-oxide and related compounds, Anal. Chem., 31, 561-565 (1959). Y. A. Gawargious and M. R. F. Ashworth, Microdetermination of the amine oxide group in organic compounds by reduction with titanium (III), Z. Anal. Chem., 256, 117-119 (1971). G. L. K. Hoh, D. O. Barlow, A. F. Chadwick, D. B. Lake, and S. R. Sheeran, Hydrogen peroxide oxidation of tertiary amines. J. Am. Oil Chem. Sot., 40, 268-271 (1963). D. B. Lake and G. L. K. Hoh, Recent advances in fatty amine oxides. Part I: Chemistry and prepara- tion, J. Am. Oil ½hem. Sot., 40, 628-631 (1963). Q. F. Seaton, C. W. Lawley and H. A. Akers, The reduction of aliphatic and aromatic N-oxides to the corresponding amines with titanium (III) chloride, Anal. Blochem., 138, 238-241 (1984). E. Glynn, Reductometric determination of the sulphoxide and amine oxide groups, Analyst, 72, 248-250 (1947). H. H6ft and H. Schultze, Zur Frage der jodometrischen Bestimmung einiger Aminoxide, J. Prakt. Chem., 19, 260-265 (1963). H. Y. Lew, Analysis of detergent mixtures containing amine oxides, J. Am. Oil Chem. Soc., 41, 297-300 (1964). M. E. Turney and D. W. Cannell, Alkaline methylene blue method for determination of anionic surfactants and for amine oxides in detergents, J. Am. Oil Chem. Soc. 42, 544-546 (1965). T. M. Muzyczko, S. Shore, and J. A. Loboda, Fatty amidoamine derivatives: N,N-dimethyl-N-(3- alkylamidopropyl)amines and their salts, J. Am. Oil Chem. Soc., 45, 720-725 (1968). A. C. Cope, T. T. Foster, and P. H. Towle, Thermal decomposition of amine oxides to olefins and dialkylhydroxylamines, J. Am. Chem. Soc., 71, 3929-3935 (1949). G. P. Shulman and W. E. Link, Thermal decomposition of dimethyllaurylamine oxide, J. Am. Oil Chem. Sot., 41, 329-331 (1964). A. C. Cope and P. H. Towle, Rearrangement of allyldialkylamine oxides and benzyldimethylamine oxide, J. Am. Chem. Sot., 71, 3423-3428 (1949). N. Castagnoli, J. C. Craig, A. P. Melikan, and S. K. Roy, Amine-N-oxide rearrangements, mecha- nism and products of thermolysis, Tetrahedron, 26, 4319-4327 (1970). R. F. Kleinschmidt and A. C. Cope, Rearrangement of ally! groups in dyad systems, amine oxides, J. Am. Chem. Soc., 66, 1929-1933 (1944). M. Moriwaki, Y. Yamamoto, J. Oda, and Y. Inouye, Self-immolative asymmetric synthesis. I. Allylic rearrangement of optically active amine oxide, J. Org. Chem., 41, 300-303 (1976). J. Zf•vada, J. Krupi•ka, and J. Sicher, Stereochemical studies. XXXIX. The effect of ring size on the rate of formation of cis- and trans-cycloalkenes from cycloalkyldimethylamine oxides, Coll. Czech. Chem. Commun., 31, 4273-4284 (1966). M. R. V. Sahyun and D. J. Cram, Studies in stereochemistry. XXXV. Mechanism of E i reaction of amine oxides, J. Am. Chem. Sot., 85, 1263-1268 (1963).
j. Soc. Cosmet. Chem., 39, 77-80 (January/February 1988) Abstracts The Annual Scientific Meetings and Seminars of the Society of Cosmetic Chemists are important venues for informing the participants about the state of the art and recent technical advances in the field of Cosmetic Science. To provide broader dissemination of that information, the Publi- cations Committee has decided to publish abstracts of the technical presentations made at these Meetings and Seminar in theJournaL--The Editor. Society of Cosmetic Chemists Annual Seminar May 5-6, 1988 Hyatt Regency, Minneapolis, Minnesota Program arranged by the Society's Committee on Scientific Affairs Morton Pader, Ph.D., Chairman, 1988 SESSION A MOLECULAR DESIGN OF INGREDIENTS FOR PERSONAL CARE PRODUCTS carbon compatibility further. Comparative data on some acrylate resins are presented. New polymers for hair care products F. Vogel, Ph.D., and F. Frosch, Ph.D., BASF Ak- tiengesellschaft, MEF/D-H 201, 6700 Ludwig- shaferdRh., West Germany Recent market trends require hair care resins with improved hold characteristics. New resins which fill these market needs are discussed for aqueous and alcoholic applications. In water-soluble resins, vari- ation of the molecular weight of polyquaternium- 16 leads to the required hardness maintaining impor- tant other product properties, and variation of the monomer composition correlates directly to condi- tioning efficacy. In the case of alcohol-soluble resins, the introduction of a third monomer into traditional copolymers results in a remarkable change of properties. The influence of the variation of monomer ratios upon the hydrocarbon tolerance of vinylpyrrolidone terpolymers and other polymer systems was investigated and results are presented in the case of vinylprrolidone/vinylacetate/vinylpro- pionate terpolymers, an optimal ratio was found at 30/40/30. The introduction of other functional groups, i.e., amides, increases hardness and hydro- Pyrrolidone-based surfactants Robert B. Login, Ph.D., GAF, 137 Page Dr., Oakland, NJ 07436 Pyrrolidone, a highly polar hydrophilic lactam structure, can be incorporated into a variety of sur- factant molecules to afford auxilliaries of unique in- terest to formulatots of personal care products. Pyr- rolidone-based surfactants can contribute condi- tioning, complexing, thickening, and foam stabilizing in a wide variety of end-use applications. In addition, the extensive toxicity studies con- ducted so far indicate a high level of safety. Surfa- done TM LP (N-Alkylpyrrolidones) are commerical examples of this class of surfactant. Development of hydrocarbon-tolerant polymers for hairsprays William M. Rouse 3 and Frank A. Nowak, Na- tional Starch and Chemical Corporation, Finderne Avenue, Bridgewater, NJ 08807 Recent trends in aerosol hairspray formulation have created markets for new fixative polymers. World- wide movement toward higher solids, CFC elimina- 77
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