POLYMER/SURFACTANT INTERACTION 47 Figure 17. Depiction of associating polymer structure with surfactant miceliar bridge (Courtesy D. R. Bassett). The effects noted above can be magnified (or at least substantially altered) if a surfactant is also present in the system, since the presence of additional hydrophobic groups vir- tually guarantees that association between the two species will occur. (See Figure 17, which depicts a possible association structure.) In this vein, Ananthapadmanabhan et al. (68) showed that the addition of a very small amount of SDS was able to substantially increase the solubilizing power of the polymer polyquaternium 24 for a fluorescent dye. Changes in other properties of the association polymer can be expected, and obviously the number of variations possible on this basic theme is very large. While current interest in this area is largely confined to the paint and petroleum industries, its wider implications and opportunities for exploitation are substantial and certainly include the cosmetics industry. REFERENCES (1) M. M. Breuer and I.D. Robb, Chem. Ind., 530 (1972). (2) I.D. Robb, in Anionic Surfactants in Physical Chemistry of Surfactant Action, E. H. Lucassen-Reynders, Ed. (Dekker, New York, 1981), p. 109. (3) E. D. Goddard, Colloids andSurfaces, 19, 255, 301 (1986). (4) Lipo-Proteins, Discuss. Faraday Soc., 6 (1949). See article by D. G. Dervichian. (5) P. J. Flory, Principles of Polymer Chemistry (Cornell University Press, Ithaca, NY, 1953). (6) M. N. Jones, J. Colloid Interface Sci., 23, 36 (1967). (7) M. J. Schwuger, J. Colloid Interface Sci., 43, 491 (1973). (8) H. Lange, KolloidZ. Z. Polym., 243, 10! (1971).
48 JOURNAL OF THE SOCIETY OF COSMETIC CHEMISTS (19) (20) (21) (22) (23) (24) (25) (26) (27) (28) (29) (30) (31) (32) (33) (34) (35) (36) (37) (38) (40) (41) (42) (43) (44) (45) (46) (47) (48) (49) (50) (51) (52) (53) (54) (55) (56) (57) (58) (59) (60) (9) M. J. Schwuger and H. Lange, ?roc. 5th Int. Congr. of Surface Act. Agents, Barcelona, 1968 (Ediciones Unidas S.A., Barcelona, 1969), Vol. 2, p. 955. (10) H. Arai, M. Murata, and K. Shinoda, J. ColloidlnterfaceSci., 37, 223 (1971). (11) M. Murata and H. Arai,J. ColloidlnterfaceSci., 44, 475 (1973). (12) E. D. Goddard, T. S. Phillips, and R. B. Hannan, J. Soc. Cosmet. Chem., 26, 461 (1975). (13) E. D. Goddard and R. B. Hannan, J. ColloidlnterfaceSci., 55, 73 (1976). (14) K. Shirahama, ½olloid Polym. Sci., 252, 978 (1974). (15) K. Ohbu, O. Hiraishi, and I. Kashiwa, J. Am. Oil Chem. Soc., 59, 108 (1982). (16) G. C. Kresheck and I. Constantinidis, Anal. Chem., 56, 152 (1984). (17) B. J. Birch, D. E. Clarke, R. S. Lee, andJ. Oakes, Anal. Chim. Acta, 70, 417 (1974). (18) A. Malovikova, K. Hayakawa, and J. C. T. Kwak, in "Structure Performance Relationships in Sur- factants," M. J. Rosen, Ed. A½S Symposium Ser., 253, 225 (1984). K. Hayakawa, J.P. Santerre, and J. C. T. Kwak, Macromolecules, 16, 1642 (1983). N. Muller and T. W. Johnson, J. Phys. Chem., 73, 2042 (1969). M. L. Smith and N. Muller, J. ColloidlnterfaceSci., 52, 507 (1975). B. Cabane, J. Phys. Chem., 81, 1639 (1977). T. Sasaki, K. Kushima, K. Matsuda, and H. Suzuki, Bull. Chem. Soc. Jpn., 53, 1864 (1980). S. Saito and M. Yukawa, J. Colloid Interface Sci., 30, 211 (1969). S. Saito, J. Colloid Interface Sci., 15, 283 (1960). K. Shirahama and N. Ide, J. ColloidlnterfaceSci., 54, 450 (1976). E. D. Goddard and R. B. Hannan, J. Am. Oil Chem. Soc., 54, 561 (1977). B. Cabane and R. Duplessix, J. Physique, 43, 1529 (1982). A. Malovikova, K. Hayakawa, andJ. C. T. Kwak, J. Phys. Chem., 88, 1930 (1984). K. Hayakawa and J. C. T. Kwak, J. Phys. ½hem., 87, 506 (1983). A. Carlsson, G. Karlstrom, and B. Lindman, J. Phys. Chem., 93, 3673 (1989). K. E. Lewis and C. P. Robinson, J. ColloidlnterfaceSci., 32, 539 (1970). R. H. Pelton, Private Communication. N. Murai, S. Makino, and S. Sugai, J. Colloid Interface Sci., 41, 399 (1972). R. Nagarajan, Colloids and Surfaces, 13, 1 (1985). T. Gilanyi and E. Wolfram, Colloids and Surfaces, 3, 181 (1981). D. M. Bloor and E. Wyn-Jones, J. ½hem. Soc. Faraday Trans. 2, 78, 657 (1982). J. Gettings, C. Gould, D. G. Hall, P. L. Jobling, J. Rassing, and E. Wyn-Jones, J. Chem. Soc. Faraday Trans. 2, 76, 1535 (1980). (39) D. M. Bloor, W. Knoche, and E. Wyn-Jones, "VC50, Techniques and Applications Fast Reactions in Solution," NATO Adv. Study Inst. Ser., Ser. C. (NASCDS) (D. Reidel, Dordrecht, 1979), p. 265. K. Shirahama, K. Tsujii, and T. Takagi, J. Biochem. (Tokyo), 75, 309 (1974). L. M. Landoll, Private Communication. I. Satake and J. T. Yang, Biopolymers, 15, 2263 (1976). K. Shirahama, H. Yuasa, and S. Sugimoto, Bull. Chem. Soc. Jpn., 54, 375 (1981). K. Shirahama and M. Tashiro, Bull. Chem. Soc. Jpn., 57, 377 (1984). A. Delville, Chem. Phys. Lett., 118, 617 (1985). J. Francois, J. Dayantis, and J. Sabbadin, Eur. Polym. J., 21, 165 (1985). P.S. Leung, E. D. Goddard, C. Han, and C. J. Glinka, Colloids and Surfaces, 13, 47 (1985). K. Takeda, Bull. Chem. Soc. Jpn., 58, 1210 (1985). R. Y. Lochhead, D. S. Warfield, and C. Gasiewski, Polymer Eng. andSci., 25, 1110 (1985). S. Saito, KolloidZ., 154, 19 (1957). M. N. Jones, J. Colloid lnterfaceSci., 26, 532 (1968). N.J. Turro, B. H. Baretz, and P. L. Kuo, Macromolecules, 17, 1321 (1984). T. Isemura and A. Imanishi, J. Polym. Sci., 33, 337 (1958). P. L. Dubin and D. Davis, Colloids and Surfaces, 13, 113 (1985). M. Yu. Pletnev and A. A. Trapeznikov, Kolloidn. Zh., 40, 948 (1978). A. Carlsson, G. Karlstrom, and B. Lindman, Langmuir, 2, 536 (1986). F. Xie, C. Ma, and T. Gu, Colloids and Surfaces, 36, 39 (1989). L. D. Rhein, C. R. Robbins, K. Fernee, and R. Cantore, J. Soc. Cosmetic Chem., 37, 125 (1986). F. J. Prescott, E. Hahnel, and D. Day, Drug and Cosmetic Industry, 93, 443 (1963). J. B. Ward and G. J. Sperandio, J. Soc. Cosmetic Chem., 15, 327 (1964).
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