272 JOURNAL OF COSMETIC SCIENCE
Precise recommendations to obtain an optimized HIP gel-in-oil emulsion could be
established, concerning both the composition (minimum viscosity of the internal gel
phase and associated dose of rheology modifier minimum concentration of emulsifier
ratio between the two phases) and the preparation of the formulation. A mixing procedure
with medium shear using planetary devices, such as an anchor, during emulsification was
essential for the creation of the HIP formula.
The HIP gel-in-oil concept opens up formulation prospects thanks to its sustainable cold
manufacturing process, aesthetics with fresh first contact, and proven benefits for skin
applications.
ACKNOWLEDGMENTS
AUTHOR CONTRIBUTIONS
Liming Sun: conceptualization, methodology, investigation, validation, formal analysis,
data curation, writing—original draft, review and editing Carla Perez: conceptualization,
supervision, project administration, review Alicia Roso: conceptualization, formal
analysis, writing—original draft, review and editing, visualization.
REFERENCES
(1) Bago Rodriguez AM, Binks BP. High internal phase Pickering emulsions. Curr Opin Colloid Interface Sci.
2022 57:101556. doi: 10.1016/j.cocis.2021.101556
(2) Zhang T, Sanguramath RA, Israel S, Silverstein MS. Emulsion templating: porous polymers and beyond.
Macromolecules 2019 52(15): 5445–5479.
(3) Zhang Y, Xie Y, Liu H, et al. Probiotic encapsulation in water-in-oil high internal phase emulsions:
enhancement of viability under food and gastrointestinal conditions. Food Sci Technol. 2022 163:113499.
doi: 10.1016/j.lwt.2022.113499
(4) Lee MC, Dadmohammadi Y, Tan C, Abbaspourrad A. Mitigating the astringency of acidified whey
protein in proteinaceous high internal phase emulsions, ACS Appl Bio Mater. 2020 3(12):8438–8445.
(5) Wu X, Xu N, Cheng C, et al. Encapsulation of hydrophobic capsaicin within the aqueous phase
of water-in-oil high internal phase emulsions: controlled release, reduced irritation, and enhanced
bioaccessibility. Food Hydrocoll. 2022 123:107184. doi: 10.1016/j.foodhyd.2021.107184
(6) Mwangi WW, Lim HP, Low LE, Tey BT, Chan ES. Food-grade Pickering emulsions for encapsulation
and delivery of bioactives. Trends Food Sci Technol. 2020 100:320–332.
(7) Okuro PK, Gomes A, Costa ALR, Adame MA, Cunha R. Formation and stability of W/O-high internal
phase emulsions (HIPEs) and derived O/W emulsions stabilized by PGPR and lecithin. Food Res Int.
2019 122:252–262.
(8) Lee MC, Tan C, Ravanfar R, Abbaspourrad A. Ultrastable water-in-oil high internal phase
emulsions featuring interfacial and biphasic network stabilization. ACS Appl Mater Interfaces
2019 11(29):26433–26441.
(9) Silva TJ, Barrera-Arellano D, Ribeiro APB. Oleogel-based emulsions: concepts, structuring agents, and
applications in food. J Food Sci. 2021 86(7):2785–2801.
(10) Tang XY, Wang ZM, Yu DI, et al. Fabrication of ultrastable water-in-oil high internal phase emulsion
as versatile delivery vehicle through synergetic stabilization. Food Hydrocoll. 2022 126:107455. doi:
10.1016/j.foodhyd.2021.107455
Precise recommendations to obtain an optimized HIP gel-in-oil emulsion could be
established, concerning both the composition (minimum viscosity of the internal gel
phase and associated dose of rheology modifier minimum concentration of emulsifier
ratio between the two phases) and the preparation of the formulation. A mixing procedure
with medium shear using planetary devices, such as an anchor, during emulsification was
essential for the creation of the HIP formula.
The HIP gel-in-oil concept opens up formulation prospects thanks to its sustainable cold
manufacturing process, aesthetics with fresh first contact, and proven benefits for skin
applications.
ACKNOWLEDGMENTS
AUTHOR CONTRIBUTIONS
Liming Sun: conceptualization, methodology, investigation, validation, formal analysis,
data curation, writing—original draft, review and editing Carla Perez: conceptualization,
supervision, project administration, review Alicia Roso: conceptualization, formal
analysis, writing—original draft, review and editing, visualization.
REFERENCES
(1) Bago Rodriguez AM, Binks BP. High internal phase Pickering emulsions. Curr Opin Colloid Interface Sci.
2022 57:101556. doi: 10.1016/j.cocis.2021.101556
(2) Zhang T, Sanguramath RA, Israel S, Silverstein MS. Emulsion templating: porous polymers and beyond.
Macromolecules 2019 52(15): 5445–5479.
(3) Zhang Y, Xie Y, Liu H, et al. Probiotic encapsulation in water-in-oil high internal phase emulsions:
enhancement of viability under food and gastrointestinal conditions. Food Sci Technol. 2022 163:113499.
doi: 10.1016/j.lwt.2022.113499
(4) Lee MC, Dadmohammadi Y, Tan C, Abbaspourrad A. Mitigating the astringency of acidified whey
protein in proteinaceous high internal phase emulsions, ACS Appl Bio Mater. 2020 3(12):8438–8445.
(5) Wu X, Xu N, Cheng C, et al. Encapsulation of hydrophobic capsaicin within the aqueous phase
of water-in-oil high internal phase emulsions: controlled release, reduced irritation, and enhanced
bioaccessibility. Food Hydrocoll. 2022 123:107184. doi: 10.1016/j.foodhyd.2021.107184
(6) Mwangi WW, Lim HP, Low LE, Tey BT, Chan ES. Food-grade Pickering emulsions for encapsulation
and delivery of bioactives. Trends Food Sci Technol. 2020 100:320–332.
(7) Okuro PK, Gomes A, Costa ALR, Adame MA, Cunha R. Formation and stability of W/O-high internal
phase emulsions (HIPEs) and derived O/W emulsions stabilized by PGPR and lecithin. Food Res Int.
2019 122:252–262.
(8) Lee MC, Tan C, Ravanfar R, Abbaspourrad A. Ultrastable water-in-oil high internal phase
emulsions featuring interfacial and biphasic network stabilization. ACS Appl Mater Interfaces
2019 11(29):26433–26441.
(9) Silva TJ, Barrera-Arellano D, Ribeiro APB. Oleogel-based emulsions: concepts, structuring agents, and
applications in food. J Food Sci. 2021 86(7):2785–2801.
(10) Tang XY, Wang ZM, Yu DI, et al. Fabrication of ultrastable water-in-oil high internal phase emulsion
as versatile delivery vehicle through synergetic stabilization. Food Hydrocoll. 2022 126:107455. doi:
10.1016/j.foodhyd.2021.107455








































































