62 JOURNAL OF COSMETIC SCIENCE
at ambient temperature with a rotation rate of 30 rpm and applied torque in the range of
34.9 and 98.9%.
Product performance reviews of solid format body wash formulations featuring OFS
were collected by mailing powder formulation samples to a pre-screened user group,
focusing on users who already used standard body wash gel on a regular basis. Sample size
kits were mailed to users and contained a reusable bottle, one sachet of body wash powder,
instructions for use, and a QR code for providing feedback via an online survey. Questions
focused on rating the product viscosity, the creamy texture of the product, the level of
foam/lather generated during use, their rating of the fragrance, and the skin feel after
rinsing. Across all metrics, users were asked to compare the sample with their favorite body
wash gel product on a scale from 1–5. In addition, users were asked to select adjectives to
describe their experience preparing the hydrated body wash gel, their experience washing
with the product, the visual quality of the product, and the overall user experience. A total
of 14 survey respondents were considered in the OFS body wash product reviews.
CARBON EMISSION REDUCTION ESTIMATES
To determine the approximate reduction in carbon emissions for OFS surfactant
manufacturing compared to the start-of-the-art, Sironix contracted an environmental
sustainability consultant to provide a screening life cycle analysis for the OFS production
process, with direct comparison to the current commercial sodium lauryl ether sulfate
manufacturing process. For this study, the objective was to determine climate impact and
identify environmental hotspots for OFS in comparison to SLES system boundaries were
cradle-to-gate with impact categories including climate change [kg CO2 eq.], acidification
potential [mol H+ eq.], eutrophication freshwater [kg P eq], non-renewable energy resource
depletion [MJ], land use [points], and blue water consumption [kg]. LCA FE/GaBi software
was used. Secondary data from standard LCI databases Sphera Managed LCA content and
ecoinvent 3.8 Data gaps are closed with proxies. Geographic constraints were for surfactant
production in the US, though European or Global datasets were used in some cases when
US specific datasets were unavailable.
FORMULATION COMPATIBILITY AND BENEFITS OF OFS SURFACTANTS
Consumers interact with personal care products most frequently and closely, with shampoo,
body wash, and facial cleanser as prime examples. Anionic surfactants serve a central role in
formulating these products. They provide the foam consumers enjoy during application, a
balance of cleaning power to remove soils and a positive sensory experience for the consumer.
Formulators have relied on SLS for personal care products to achieve an optimal balance of
these properties using fully bio-renewable anionic surfactants.19Asmentioned,thissurfactant
has poor performance in hard and cold water, and as a dermal irritant, use in applications
involving direct skin contact can be challenging for product formulators.20,21 Ether sulfate
surfactants, such as SLES, have long served as a reasonable substitution, providing high
performance and less irritation in personal care.22 Should the implementation of more
stringent regulations continue to decrease the allowable dioxane content in consumer
products, the combination of increasing production costs and regulatory restrictions may
curtail use of SLES by personal care product formulators.
63 Oleo-Furan Sulfonates
OFS surfactants provide a low carbon alternative petrochemical-based anionic surfactants
while also demonstrating improved properties compared to commercial plant-based
anionic surfactants such as SLS (Table I). CMC and surface tension are metrics commonly
used to determine the surfactant concentration required to achieve micelle formation and
the level of surfactant effect for use in consumer products. In comparison to the leading
petrochemical surfactants, OFS was found to have similar values for surface tension and
CMC, with a significantly lower CMC value compared to the plant-based commercial
surfactant, SLS. Foam generation, measured by both Ross-Miles and high shear test
methods, found exceptionally high levels of foam formed by OFS only exceeded by SLS,
with excellent foam stability.
Krafft point, the temperature above which ionic surfactants are readily solubilized and are
optimally functional for micelle creation, provides an indication of which anionic surfactants
are ideal for use at low temperatures. Depending on the climate where products are being
used and the product storage location, surfactants can be observed to precipitate out of the
product formulation if temperatures are sufficiently low or insufficient solubilizers were
incorporated. OFS surfactants and SLES have exceptional solubility at temperatures down
to 0°C, while both LAS and SLS experience solubility limitations at temperatures below
20°C and 15°C, respectively. To demonstrate surfactant solubility limits in hard water, 0.5
wt% surfactant solutions were titrated with a calcium chloride solution the concentration
at which a precipitate is formed is identified as the hard water tolerance in Figure 4A. Both
SLS (35 ppm Ca2+) and LAS (100 ppm Ca2+) were found to precipitate from solution at
calcium concentrations 500x lower than the 100,000 ppm test limit, while OFS and SLES
remained soluble at the highest calcium concentration tested.
Table I
Select Properties of The Oleo-Furan Sulfonate Surfactant Sodium Lauroyl Methylfuran Sulfonate With
Comparison to Commercial Anionic Surfactants
Surfactant CMC
(ppm)1
Surface
Tension
(mN/m)2
Ross Miles
Foam
Height
(mm)3
High Shear
Foam
Height
(mm)4
Wetting
Time
(sec)5
Krafft
Point
(°C)
Sulfate
Free
Dioxane
Free
Sodium Lauroyl
Methylfuran Sulfonate
799 34 170 /165 75 /75 8 0
Sodium Lauryl
Ether Sulfate
4496 326 160 /150 50 /48 15 0 X X
Sodium Dodecyl
Benzene Sulfonate
8367 35 145 /140 63 /62 5 20
Sodium Lauryl
Sulfate
23,657 31 180 /170 80 /78 6 15 X
1 Critical micelle concentration of surfactant in deionized water at room temperature (25°C)
2 Surface tension at CMC
3 Height of foam after initial formation and after 5 minutes (20°C) for 0.1 wt% surfactant following ASTM
D1173
4 Height of foam after initial formation and after 5 minutes (20°C) for 0.1 wt% surfactant following ASTM
D3519
5 Wetting of cotton skein in a 0.25 wt% surfactant solution at 30°C according to ASTM D2281
6 Value reported by vendor (STEOL CS330)23
7 Values reported in literature for SDBS24 and SLS25
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