JOURNAL OF COSMETIC SCIENCE 188 Figure 9. FT-IR derived ratio of polymer in foam phase to liquid phase. Figure 8. FT-IR of polymers and surfactant. coacervates, form upon dilution of a concentrated polymer/surfactant solution, and de- posit directly onto the hair and skin to provide conditioning effects as well as deposit other molecules to achieve lasting feel. These complexes are found in the foam and liq- uid phases. Our experiments, reported here, have shown that there is no preferential concentration of polymer in the foam phase compared to the liquid phase for all of the polymers studied. We conclude, therefore, that foam fractionation of the polymer/sur- factant coacervate is unlikely to be an important factor in the topical delivery of these coacervates. ACKNOWLEDGMENTS The authors are grateful for technical assistance and scientifi c advice from E.D. Smith and S. McConaughy of Procter & Gamble.
2010 TRI/PRINCETON CONFERENCE 189 Our research results are based upon work supported by the National Science Foundation Partnerships for Innovation (PFI) Program under Grant No. PFI Award 0917730. Any opinions, fi ndings, and conclusions or recommendations expressed in this material are those of the author(s) and do not necessarily refl ect the views of the National Science Foundation. REFERENCES (1) K. Klein, Cosmet. Toiletr., 32–34 (October 2004). (2) E. D. Goddard and J. V. Gruber, Principles of Polymer Science and Technology in Cosmetics and Personal Care (CRC Press, 1999), pp. 181–185. (3) Y. Wang, K. Kimura, Q. Huang, P. L. Dubin, and W. Jaeger, Macromolecules, 32, 7128 (1999). (4) C. Robbins, Chemical and Physical Behavior of Human Hair, 4th ed. (Springer-Verlag, New York, 2002), pp. 352–360. (5) E. D. Goddard, T. S. Phillips, and R. B. Hannan, J. Soc. Cosmet. Chem., 26, 461 (1975). (6) E. D. Goddard and R. B. Hannan, J. Am. Oil Chem. Soc., 54, 561 (1977). (7) E. D. Goddard and K. P. Ananthapadmanabhan, Interactions of Surfactants with Polymers and Proteins (CRC Press, Boca Raton, F1, 1993), Ch. 2–4. (8) E. G. Cockbain, Transactions of the Faraday Society, 49, 104 (1953). (9) W. J. Knox and T. O. Parshall, J. Colloid Interface Sci., 33, 16 (1970). (10) K. Holmberg, B. Jonsson, B. Kronberg, and B. Lindman, Surfactants and Polymers in Aqueous Solution. 2nd ed. ( John Wiley & Sons Ltd., West Sussex, England, 2003). (11) C. Wang and K. C. Tam, Langmuir, 18, 6484–6490 (2000). (12) M. R. Rosen, Delivery System Handbook for Personal Care and Cosmetic Products (William Andrew, Inc., Norwich, N.Y., 2005) pp. 501–510.
Purchased for the exclusive use of nofirst nolast (unknown) From: SCC Media Library & Resource Center (library.scconline.org)





































































































































































































