440 JOURNAL OF COSMETIC SCIENCE
bonds necessitates reactive chemistry, which in turn produces all manner of safety and
regulatory issues. Furthermore, new covalent bonds may not necessarily be advantageous.
Formaldehyde is a chemical that has long been reported to produce new protein crosslinking
in wool and hair40 and has been utilized as a means of permanently straightening hair via
so-called Brazilian Keratin treatments (notwithstanding the serious health implications).
Such treatments can be highly effective, but also result in a dramatic reduction of tensile
properties. It again seems likely that this new term/proposition involves wordsmithing
around the previously discussed relationship between the consumer perception of strength
(i.e., finding broken fibers) and the ability for sizable mitigation via lubricating conditioner
treatments.
In a similar vein, such lubrication can reasonably be expected to help slow certain pathways
of hair’s progressive degradation. Specifically, fibers will be exposed to lesser abrasion and
fatiguing during grooming and other forms of manipulation. This would seem to be a
reasonable and sound foundation for hair protection propositions.
HAIR TYPE
The appearance of hair can vary greatly from one individual to the next. Individual fibers
come in a wide variety of sizes, shapes, and colors and there appears a general presumption
among consumers that such differences must be the consequence of differing makeup. This
leads to the well-entrenched industry concept of “hair type” and the desire to pigeonhole
hair based on any one of a variety of variables (e.g., ethnicity, curl type, color, thickness,
etc.). Yet, historical technical evidence does not support this stance. The overall structure of
all hair abides by the schematic shown in Figure 5, and no general agreement exists among
numerous literature studies that have explored supposed compositional differences in terms
of amino acid levels.5–7 For all its variability, hair would appear to have the same general
makeup no matter how it is classified.
There is strong evidence to suggest that the fundamental shape of hair fibers is dictated by
the manner with which it grows within the follicle.41 Straight hair grows out of straight
follicles and from a symmetrical bulb curly hair grows from curved follicles and an
unsymmetrical bulb. Hair’s natural color is the consequence of melanin pigment granules
located within the cortex higher concentrations produce progressively darker hair, while
low levels produce lighter hair. Despite, the obvious effect on visual properties, the overall
low relative concentrations of melanin, in even the most heavily pigmented hair, leads to
a belief that its presence has no meaningful effect on physical properties. It is not unusual
to find hair fibers with dimensions anywhere between approximately 50 to 100 µm in
diameter yet, they still have the same fundamental structure. Thicker fibers tend to
have a hollow-like center, termed the medulla, which was traditionally thought to have
no meaningful contribution to hair properties. Returning to an earlier point about hair’s
primordial function of keeping the wearer warm, this hollow-like center might be expected
to increase insulating capacity. However, in recent years, we have learned this structure
has a high lipid content,42 which is leading to a rethinking of the passive nature of this
structure. So, while size, shape, and color can make hair look and behave differently, it’s not
because the hair is made of radically different stuff.
It’s worth considering how these seemingly passive properties can sizably impact hair’s
fundamental attributes. Thicker fibers will weigh more, which impacts the way the hair
441 SUSTAINABLE HAIR
hangs from the head and moves. Increasing fiber curvature will increase interactions with
neighbors and similarly affect these two properties. In more extreme cases, manageability
might become an issue while also potentially restricting the ability to create certain styles.
All things being equal, thicker fibers will have higher mechanical properties: thicker hair
necessitates higher bending forces and higher extensional forces to cause breakage. In
short, vastly different hair array properties can be explained without requiring structural
differences.
This holds true even for extremely curly hair of African origin, which is prone to many
cosmetic issues.23 In addition to the tight curls, this hair can have a highly elliptical cross-
section, which may also twist down the length of the fiber (see Figure 15). Most obviously,
the extreme conformation leads to grooming issues and style restrictions. In this hair type,
overall array properties essentially relate to interactions involving thousands of irregularly
shaped spring-like fibers, as compared to the more uniform, rod-like strands in straight hair.
Again, it can be seen how dramatically different properties will result without structural
differences. The ellipticity and twisting might be expected to affect tactile properties, such
that individual fibers don’t feel as smooth. The combination of this high curl, the high
ellipticity and the twisting has long been suspected to produce points of high localized
stresses in fibers where flaws and cracks might form. These weaknesses may then propagate
rapidly to produce the high propensity for hair breakage. Figure 15 also seems to show an
example of this occurrence as large longitudinal cracks can be seen going into and out of
the twist.
While it is commonplace to try and pigeonhole hair, it is again worth mentioning the
extreme variability of this substrate. For example, it is commonly heard that Asian hair is
thicker than Caucasian hair Figure 16 shows this author’s results for statistical distributions
obtained from measuring the diameters of around 1,500 hair fibers for both hair types. The
Asian hair indeed possesses a significantly higher mean, but standard deviations are very
high. So, while Asian hair is in general thicker than Caucasian hair, it is still eminently
possible to find some Asians with quite thin hair and some Caucasians with quite thick
hair. Further to this point, there are also very high standard deviations in the dimensions of
hair from any given head.43 The above statement should therefore be considered a generality
and not a universal absolute. The same is true of many parameters that are frequently used
in such pigeonholing.
Figure 15. The twisting structure of highly curly hair of African origin.
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